A Route to Quantum-Coherent Thermodynamics

Equilibrium thermodynamics emerges because a vast number of microscopic states become indistinguishable at the level of local observables. We start from the observation that a nonequilibrium quantum state can also be represented by an ensemble of pure states that minimizes the average energy variance. We show that varying the statistical weights within this optimal family organizes state space into ``minimum-variance leaves'', which generalize the space of stationary states underlying equilibrium. We observe thermodynamic compression on the leaves, which in the simplest scenario manifests itself in the indistinguishability of states with the same energy density. We call this ``leaf typicality''; at equilibrium it reduces to eigenstate thermalization or its generalizations. Numerical tests support leaf typicality on some leaves and indicate a breakdown of its stronger forms on others, suggesting a rich thermodynamic organization beyond equilibrium. These results open a route to a unified statistical mechanics of equilibrium and nonequilibrium quantum states.