Chemistry on solar system scales

The initial chemical composition of planets, primitive bodies in our solar system, and exoplanets is ultimately set by their nascent protoplanetary disks. Yet observing key carbon-, oxygen-, and nitrogen-bearing molecules (as well as rarer but important sulphur- and phosphorus-bearing species) in the inner (exo)planet-forming zone (10 au) remains extremely challenging with current facilities. Therefore, to construct a complete picture of the chemistry of planet formation and understand how (exo)planetary composition is set by physical and chemical processes within the protoplanetary disk, a more powerful observing facility, i.e., ALMA2040, is needed. Compared to current ALMA (the Atacama Large Millimeter/submillimeter Array) this new facility must provide > a factor of 10 in line sensitivity at a spatial resolution of < 5 au at 140 pc, i.e., a factor of 3 - 4 better resolution to low surface brightness emission than currently possible. This distance includes many star-forming regions such as Taurus and Lupus that are host to populations of Sun-like stars. ALMA2040 will enable mapping of disk chemical composition on terrestrial planet-forming scales (within the water snowline) and detect molecules that are the feedstock for potentially habitable worlds.