PAHSPECS: JWST/MIRI Spectroscopy of PAHs at Cosmic Noon

The physical conditions of the interstellar medium (ISM) are thought to differ greatly at high redshifts compared to local galaxies. Polycyclic aromatic hydrocarbons (PAHs) are key ISM constituents, mediating the heating and cooling of gas in photo-dissociation regions. However, PAHs are unexplored in main-sequence (MS) galaxies at z 1-2 (cosmic noon), limiting our view of the ISM's thermal and chemical balance. We present the PAH Spectroscopic Survey (PAHSPECS) JWST program, the first MIRI/MRS survey of the 3.3, 6.2, 7.7, 8.6 and 11.3 μ m PAH features in MS galaxies at z 1. The five targets come from the deep ALMA CO and continuum flux-limited sample in the HUDF. We detect the 6.2, 7.7 and 11.3 μ m PAHs in all galaxies, and the 3.3 μ m feature in only two. Spectral energy distribution (SED) fitting to broad-band mid-IR photometry recovers the 6.2 and 7.7 μ m PAH luminosities derived from spectral decomposition of the MRS spectra to within 25% accuracy. However, the 3.3 and 11.3 μ m features are overestimated by 50% (up to 3-5x). Spatially resolved maps of ASPECS-6, the most extended source, show variations of the 7.7 μ m PAH contribution to the MIRI F1500W flux, suggesting that while photometry can infer PAH luminosity accurately, IFU spectroscopy is necessary to study variations in PAH ratios and characterize galaxy dust properties. The PAH fraction of the total dust mass from photometric SED modeling roughly agrees with the L PAH/L IR ratio measured from spectroscopy, but the correlation is not as tight as models predict. On average, PAHSPECS galaxies show an excess in 6.2 μ m equivalent width relative to nearby dusty luminous systems, but lower 3.3 μ m equivalent widths than local systems, similar to higher-mass starbursts at z 1-3. This points to differential changes in the size distributions of neutral and ionized PAHs in cosmic noon galaxies.