Direct Charge-4e Superconductivity by Mobilizing Bound Quartets

arXiv:2609.24445 · cond-mat.str-el, cond-mat.supr-con · Submitted 2026-09-21 · Read on arXiv

cond-mat.str-el, cond-mat.supr-con

Submitted: 2026-09-21

Updated: 2026-10-12

Comments: 19 pages, 2 figures

License: http://creativecommons.org/licenses/by/4.0/

The gist: A direct charge- 4e superconductor exhibits coherent four-electron order while every charge- 2e pairing channel remains uncondensed.

Terminology

Abstract

A direct charge- 4e superconductor exhibits coherent four-electron order while every charge- 2e pairing channel remains uncondensed. We establish three complementary results. First, building on the η-clustering states and bipartite parent of Yoshida and Katsura, we formulate and exactly solve a minimal two-term parent on any connected graph. Its fixed-number ground states have quartet off-diagonal long-range order (ODLRO) without charge- 2e ODLRO, while an exact mapping to classical hard-core exclusion dynamics yields the full fixed-sector gap and a branch of quartet-density modes. Nonzero quartet stiffness and vanishing inverse quartet compressibility identify this z=2 parent as a phase-separation boundary. Second, for a finite-range fermionic family with explicit quartet transfer and sufficiently large onsite penalty, we rigorously prove quartet ODLRO without charge- 2e ODLRO at half quartet filling, both at the hypercubic XY point for d at least2 and throughout a finite XXZ interval on the square lattice. Third, we derive a strong-coupling realization using only electron hopping and two-body interactions. With local gap U 0, pair hopping K generates quartet motion at order K 2/U 0, whereas electron hopping t first contributes at order t 4/U 0 cubed; charge- 2e excitations remain gapped at O(U 0). On bipartite lattices, positive inverse quartet compressibility opens an asymptotically controlled homogeneous z=1 regime with short-ranged pair correlations, while negative curvature drives phase separation.

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