Microsecond-Pulsed Nanocalorimetry: A Scalable Approach for Ultrasensitive Heat Capacity Measurements

We introduce a nanocalorimetric technique based on microsecond-pulsed heating (μs-PHnC) that enables high-sensitivity, quasi-isothermal heat capacity measurements on nanoscale samples. Such resolution is critical for exploring thermodynamic signatures in low-dimensional materials, where conventional techniques fall short. By confining thermal excitation to microsecond timescales, this approach minimizes lateral heat diffusion, reduces heat capacity addenda to below 10-9 J K-1, and achieves noise densities as low as 75 pJ K-1 Hz-1/2 mm-2, unlocking precise thermodynamic characterization of subnanogram samples in areas as small as 30 x 30 μm squared. The method delivers exceptional temperature homogeneity, as demonstrated by resolving sharp phase transitions, such as the antiferromagnetic transition in ultrathin CoO films, with unprecedented clarity. Its quasi-static operation is inherently compatible with external stimuli, including magnetic and electric fields, thereby expanding its utility for in-operando thermodynamic studies. This advancement establishes a robust and scalable platform for probing thermal phenomena in nanostructured and low-dimensional materials, significantly broadening the scope of nanocalorimetry.